You're thinking along the right track with the shunt idea. The ammeter already has a shunt built into the gauge. You're going to need to disassemble the ammeter, isolate the shunt and measure its capabilities, determine the nature of the actual gauge movement (which, like all "ammeter" movements, is actually a milliammeter), and do some electric calculations which I can't help you with, but 440_Magnum on here can. Then make your shunt (which must be of precise current capacity/resistance) out of copper or brass bar or suchlike, insulate it, and install it across the two legs of A-1/A-1A (main circuit) where they enter/exit the firewall...on the engine side.
FWIW, starting in '71 (except A-bodies) '76 (A-bodies), Mopars went to external-shunt ammeters. So, perhaps an alternate method would be to find a cop car made after '71, grab its ammeter
and shunt (no idea where they hid the shunt) and swap the movement into your car's gauge housing, if possible. Needle compatibility is probably going to trip you up on that venture.
There are gauge-rebuilding services advertising in Hemmings and elsewhere; perhaps they could offer some advice.
There is also that yutz going by "MAD Electrical", a Chevy-head who babbles ignorantly about how unreliable Mopar gauges are and says the ammeter must be replaced by a hacked-in voltmeter. Guess you can tell how highly I regard his cute little opinion.
I'll see if I can get Steve (440_Magnum) to duck in on this thread and contribute something more specific than my theoretical jabber here.
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Too many people who were born on third base actually believe they've hit a triple.
