I think the "gold standard" cap/rotor to look at would be the ones Chrysler paid extra-careful attention to. The original '60-type Slant-6 cap 1889424, used with the standard Chrysler rotor 1838516, made ground-out problems especially in cold/wet conditions. They
fixed this in '62 by releasing a service package 2448273 which contained a cap 2098765, a rotor 2098770, and a coil-to-cap cable with better-sealing boots on it. The cap's contacts were 2x (or more) wider than the ones in the original (and all current) caps, and the rotor tip was narrower and longer. A few years thereafter ('66 or so) the cap was superseded in phases by 2444690 -- same design but in an upgraded tan material with higher dielectric performance than the previous black phenolic. A fair number of these caps, both black and tan, have passed through my hands over the years; I've never set up a measuring jig like yours, but I've also never seen one of these caps ground visibly off-centre.
This cap and rotor were available in the aftermarket from NAPA as
Echlin MO-6 and MO-7; they might also have been available from other aftermarket brands (Standard/BlueStreak is a guess, but I've never seen one). Here again, I've not seen one of these Echlin MO-6 caps ground visibly off-centre.
For '68, Chrysler reverted to the narrow cap contacts (though now in the tan material, p/n 2642986) and standard "fits everything we make the distributor for" rotor. My best guess is this was a cost-saving move more than anything.
I definitely have one of the 2444690 caps, new, on shelf.
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